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A polyoxometalate-encapsulated 3D porous metal-organic pseudo-rotaxane framework.

Authors
Type
Published Article
Journal
Chemical Communications
1364-548X
Publisher
The Royal Society of Chemistry
Publication Date
Volume
46
Issue
28
Pages
5097–5099
Identifiers
DOI: 10.1039/c003048a
PMID: 20549008
Source
Medline
License
Unknown

Abstract

A novel compound, [Cu(bimb)](2)(HPW(12)O(40)) x 3 H(2)O (bimb = 1,4-bis(imidazol-1-ylmethyl)biphenyl) with a polyoxometalate-encapsulated 3D metal-organic pseudo-rotaxane framework that can be described as a 2-fold dianet topology showing well-defined 1D nano-scale tunnels, has been synthesized hydrothermally, and its de-/rehydration behavior has been investigated.

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