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Poly[diaquahexakis(dimethyl sulfoxide-kappaO)cerium [(mu(2)-hexacosaoxooctamolybdate)sodium]].

Authors
  • Chen, Li Juan
  • Lu, Can Zhong
  • Zhang, Quan Zheng
  • Chen, Shu Mei
Type
Published Article
Journal
Acta crystallographica. Section C, Crystal structure communications
Publication Date
Jun 01, 2005
Volume
61
Issue
Pt 6
Identifiers
PMID: 15930661
Source
Medline
License
Unknown

Abstract

The title compound, {[Ce(C2H6OS)6(H2O)2][NaMo8O26]}n, contains an infinite chain of beta-octamolybdate moieties linked by Na+ ions, and further linked into a two-dimensional network by [Ce(DMSO)6(H2O)2]3+ (DMSO is dimethyl sulfoxide) groups via hydrogen-bond interactions. The Ce and Na atoms are located on a twofold axis and an inversion centre, respectively.

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