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Photothermoelectric (PTE) Versus Photopyroelectric (PPE) Detection of Phase Transitions

Authors
  • Dadarlat, D.1
  • Guilmeau, E.2
  • Hadj Sahraoui, A.3, 4, 5
  • Tudoran, C.1
  • Surducan, V.1
  • Bourgès, C.2
  • Lemoine, P.2
  • 1 National R&D Institute for Isotopic and Molecular Technologies, Donat Str. 67-103, Cluj-Napoca, Romania , Cluj-Napoca (Romania)
  • 2 UMR6508 CNRS/ENSICAEN, Laboratoire CRISMAT, 6bd Marechal Juin, Caen Cedex 4, 14050, France , Caen Cedex 4 (France)
  • 3 Univ. Lille Nord de France, Lille, 59000, France , Lille (France)
  • 4 ULCO, UDSMM, Dunkerque, 59140, France , Dunkerque (France)
  • 5 Unité de Dynamique et Structure des Materiaux Moléculaires, EA 4476, Dunkerque, 59140, France , Dunkerque (France)
Type
Published Article
Journal
International Journal of Thermophysics
Publisher
Springer US
Publication Date
Mar 28, 2016
Volume
37
Issue
5
Identifiers
DOI: 10.1007/s10765-016-2059-8
Source
Springer Nature
Keywords
License
Yellow

Abstract

The photopyroelectric (PPE) technique is one of the photothermal (PT) methods mostly used for phase transitions investigations. In this paper, we want to compare the PPE results with those obtained using another, recently developed PT method [the photothermoelectric (PTE) calorimetry] for the same purpose of detecting phase transitions. The well-known ferro-paraelectric phase transition of TGS, taking place at a convenient temperature (about 49∘C\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$49\, {}^{\circ }\hbox {C}$$\end{document}), has been selected for demonstration. A comparison of the two PPE and PTE methods, both in the back detection configuration (in the special case of optically opaque sample and thermally thick regime for both sensors and sample) shows that they are equally suitable for phase transitions detection. Performing a proper calibration, the amplitude and phase of the signals can be used in order to obtain the critical behaviour of all sample’s static and dynamic thermal parameters.

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