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Photochemically Induced Cyclometalations at Simple Platinum(II) Precursors

Authors
  • Poveda, Dionisio
  • Vivancos, Ángela
  • Bautista, Delia
  • González-Herrero, Pablo
Type
Published Article
Journal
Inorganic Chemistry
Publisher
American Chemical Society
Publication Date
Apr 12, 2023
Volume
62
Issue
16
Pages
6207–6213
Identifiers
DOI: 10.1021/acs.inorgchem.3c00688
PMID: 37043617
PMCID: PMC10131227
Source
PubMed Central
Disciplines
  • Communication
License
Unknown

Abstract

Labilization of metal−ligand bonds through light irradiation at Pt(II) precursors promotes facile cyclometalation of heteroaromatic C∧N, N∧N∧C, N∧C∧N, and N∧C∧C compounds at room temperature. Advantageous photochemical protocols for the synthesis of cyclometalated Pt(II) complexes are demonstrated.

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