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Phosphinooxazolines--a new class of versatile, modular P,N-ligands for asymmetric catalysis.

Authors
Type
Published Article
Journal
Accounts of chemical research
Publication Date
Volume
33
Issue
6
Pages
336–345
Identifiers
PMID: 10891051
Source
Medline
License
Unknown

Abstract

Chiral phosphinooxazolines (PHOX ligands), which coordinate to a metal center with a N- and a P-atom, allow effective enantiocontrol in a variety of metal-catalyzed reactions. They are readily synthesized, and because of their modular structure, the steric and electronic properties can be tailored for a specific application by variation of the oxazoline ring, the backbone, and the phosphine moiety.

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