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Pb3[C6(CH3)3(CO2)3H6]2[DMF]3: first layered Pb-Kemp's triacid complex.

Authors
  • Kim, Saet Byeol
  • Lee, Dong Woo
  • Chang, Suk-Kyu
  • Ok, Kang Min
Type
Published Article
Journal
Chemical Communications
Publisher
The Royal Society of Chemistry
Publication Date
Aug 28, 2015
Volume
51
Issue
67
Pages
13166–13169
Identifiers
DOI: 10.1039/c5cc05360a
PMID: 26208140
Source
Medline
License
Unknown

Abstract

An unprecedented layered Pb-Kemp's triacid compound, Pb3[C6(CH3)3(CO2)3H6]2[DMF]3, has been synthesized. The material exhibits a selective CO2 adsorption, a reversible DMF coordination, and an intercalative hexanal addition reaction. A competing crystallization reaction under solvothermal conditions using Pb(2+) and Cd(2+) with Kemp's triacid reveals higher selectivity of Cd(2+) over Pb(2+).

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