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Palladium-catalyzed cross-coupling reactions of benzyl indium reagents with aryl iodides.

Authors
Type
Published Article
Journal
The Journal of Organic Chemistry
1520-6904
Publisher
American Chemical Society
Publication Date
Volume
74
Issue
3
Pages
1388–1390
Identifiers
DOI: 10.1021/jo802280m
PMID: 19099410
Source
Medline
License
Unknown

Abstract

Herein described is an operationally simple procedure for generating benzyl indium species from readily available benzyl bromides and indium metal followed by in situ palladium-catalyzed coupling with aryl halides. The procedure provides diarylmethanes in modest to excellent yield and tolerates a variety of functional groups in both coupling partners.

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