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Oxygenation of thiolates to S-bonded sulfinate in an iron III complex related to nitrile hydratase.

Authors
Type
Published Article
Journal
Chemical Communications
Publisher
The Royal Society of Chemistry
Publication Date
Feb 13, 2004
Issue
3
Pages
286–287
Identifiers
DOI: 10.1039/b312318a
PMID: 14740040
Source
USPC - SET - SVS
License
White

Abstract

Air oxidation of the iron(III) complex derived from (2-mercaptoisobutyryl)-4,5-dichloro-O-phenylenediamine in the presence of Et4NCN afforded the corresponding disulfinato species. With two carboxamido nitrogens trans to two S-bonded sulfinates, this complex mimics the disulfinate inactive form of Fe-NHase.

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