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Oxidative Dearomatization of Phenols and Anilines via λ3- and λ5-Iodane-Mediated Phenylation and Oxygenation

Authors
  • quideau, s.
  • pouységu, l.
  • ozanne, a.
  • gagnepain, j.
Publication Date
Jan 31, 2005
Identifiers
DOI: 10.3390/10010201
OAI: oai:mdpi.com:/1420-3049/10/1/201/
Source
MDPI
Keywords
Language
English
License
Green
External links

Abstract

Treatment of 2-methylphenols with chloro(diphenyl)-λ3-iodane led to theirregioselective dearomatizing 2-phenylation into cyclohexa-2,4-dienone derivatives via aproposed ligand coupling reaction. In the same vein of investigation, treatment of2-methylanilines with the λ5-iodane 2-iodoxybenzoic acid IBX reagent led to theirregioselective dearomatization into previously undescribed ortho-quinol imines.

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