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One-step selective synthesis of branched 1-O-alkyl-glycerol/diglycerol monoethers by catalytic reductive alkylation of ketones

Authors
  • Shi, Yan1, 2
  • Dayoub, Wissam2
  • Chen, Guo-Rong1
  • Lemaire, Marc2
  • 1 East China University of Science and Technology, Laboratory for Advanced Materials and Institute of Fine Chemicals, Shanghai, 200237, China , Shanghai (China)
  • 2 Université Lyon 1, Laboratoire de Catalyse Synthèse et Environnement, Institut de Chimie et Biochimie Moléculaires et Supramoléculaires (ICBMS), CNRS, UMR5246, 43 Boulevard du 11 Novembre 1918, Villeurbanne, 69622, France , Villeurbanne (France)
Type
Published Article
Journal
Science China Chemistry
Publisher
SP Science China Press
Publication Date
Sep 24, 2010
Volume
53
Issue
9
Pages
1953–1956
Identifiers
DOI: 10.1007/s11426-010-4054-4
Source
Springer Nature
Keywords
License
Yellow

Abstract

Branched 1-O-alkyl glycerol and diglycerol monoethers were obtained in good yields and high selectivity by a straightforward catalytic reductive alkylation of glycerol with relevant ketones in the presence of 0.5 mol% of Pd/C under 10 bar of hydrogen pressure using a Brønsted acid as the co-catalyst.

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