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Oligomerization of electron-deficient vinyl monomers through an ate-complex mechanism: a new role for b(c(6) f(5) )(3) lewis Acid.

Authors
  • Pouget, Emmanuel
  • Holgado-Garcia, Erlea
  • Vasilenko, Irina V
  • Kostjuk, Sergei V
  • Campagne, Jean Marc
  • Ganachaud, Francois
Type
Published Article
Journal
Macromolecular rapid communications
Publication Date
Jul 01, 2009
Volume
30
Issue
13
Pages
1128–1132
Identifiers
DOI: 10.1002/marc.200900173
PMID: 21706577
Source
Medline
License
Unknown

Abstract

The Lewis acid B(C(6) F(5) )(3) in combination with hydrosilanes exhibits remarkable activity in the oligomerization of sulfone- and phosphonate-based monomers. This process opens new routes to high-tech silicone-based materials, i.e., thermoplastic elastomers and heat-resistant polysiloxanes.

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