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A novel approach to the CDE ring system of pectenotoxin-4 triggered by VO(acac)(2)-induced epoxy-acetalization.

Authors
  • Carley, Sarah
  • Brimble, Margaret A
Type
Published Article
Journal
Organic Letters
Publisher
American Chemical Society
Publication Date
Feb 05, 2009
Volume
11
Issue
3
Pages
563–566
Identifiers
DOI: 10.1021/ol8025457
PMID: 19117488
Source
Medline
License
Unknown

Abstract

A novel approach to the CDE fragment of pectenotoxin-4 is described wherein the bicyclic acetal is constructed via a cascade cyclization induced by VO(acac)(2) epoxidation of a homoallylic alcohol.

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