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A new solvent polymeric membrane electrode incorporating poly(N-isopropylacrylamide) as a polymer.

Authors
  • Moriuchi-Kawakami, Takayo1
  • Kurikawa, Hiroyuki
  • Matsumoto, Hiroya
  • Shibutani, Yasuhiko
  • 1 Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 5-16-1 Omiya, Asahi, Osaka, 535-8585, Japan. [email protected] , (Japan)
Type
Published Article
Journal
The Analyst
Publisher
The Royal Society of Chemistry
Publication Date
Oct 21, 2011
Volume
136
Issue
20
Pages
4141–4143
Identifiers
DOI: 10.1039/c1an15306d
PMID: 21874202
Source
Medline
License
Unknown

Abstract

Here, we report on a new solvent polymeric membrane electrode incorporating thermoresponsive poly(N-isopropylacrylamide) (PIPA) as a polymer with the lower critical solution temperature (LCST) of ca. 32 °C. The response of the solvent polymeric membrane electrode to the ions changes at 25 and 40 °C. Pulsed NMR analyses demonstrated the novel effects of the LCST behaviour on the potentiometric polymeric membrane.

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