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New polynuclear U(IV)-U(V) complexes from U(IV) mediated uranyl(V) disproportionation.

Authors
  • Mougel, Victor
  • Pécaut, Jacques
  • Mazzanti, Marinella
Type
Published Article
Journal
Chemical Communications
Publisher
The Royal Society of Chemistry
Publication Date
Jan 21, 2012
Volume
48
Issue
6
Pages
868–870
Identifiers
DOI: 10.1039/c1cc16646h
PMID: 22134746
Source
Medline
License
Unknown

Abstract

U(IV) promotes the disproportionation of otherwise stable uranyl(V) Schiff base complexes affording U(IV)-U(V) oxo clusters with new geometries and the first example of a U(IV)···UO(2)(+) cation-cation interaction.

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