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A new hybrid organic-inorganic chain: [(phen)Cu-μ-(κ2O:O'-VP2O10H3)2-Cu(phen)]n.

Authors
Type
Published Article
Journal
Acta Crystallographica Section C Crystal Structure Communications
1600-5759
Publisher
International Union of Crystallography
Publication Date
Volume
68
Issue
Pt 7
Identifiers
DOI: 10.1107/S0108270112026005
PMID: 22763689
Source
Medline
License
Unknown

Abstract

The structure of the title compound, poly[(dihydrogenphosphato-κO)(μ(3)-hydrogenphosphato)di-μ-oxido-(1,10-phenanthroline)copper(II)vanadium(V)], [CuV(HPO(4))(H(2)PO(4))O(2)(C(12)H(8)N(2))](n), is defined by [(phen)Cu-μ-(κ(2)O:O'-VP(2)O(10)H(3))(2)-Cu(phen)] units (phen is 1,10-phenanthroline), which are connected to neighbouring units through vanadyl bridges. Neighbouring chains have no covalent bonds between them, although they interdigitate through the phen groups via π-π interactions.

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