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A new [3]rotaxane molecular machine based on a dibenzylammonium ion and a triazolium station.

Authors
Type
Published Article
Journal
Organic letters
Publication Date
Volume
12
Issue
19
Pages
4248–4251
Identifiers
DOI: 10.1021/ol101920b
PMID: 20828189
Source
Medline

Abstract

A novel two-station [3]rotaxane molecular machine based on triptycene-derived macrotricyclic host was conveniently synthesized by the click reaction and methylation of the subsequent 1,2,3-tiazole group. The shuttle process of the [3]rotaxane molecular machine can be reversibly achieved by acid-base control.

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