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Naphthol synthesis: annulation of nitrones with alkynes via rhodium(iii)-catalyzed C-H activation.

Authors
  • Wang, Qiang1
  • Xu, Youwei
  • Yang, Xifa
  • Li, Yunyun
  • Li, Xingwei
Type
Published Article
Journal
Chemical Communications
Publisher
The Royal Society of Chemistry
Publication Date
Aug 23, 2017
Volume
53
Issue
69
Pages
9640–9643
Identifiers
DOI: 10.1039/c7cc05000c
PMID: 28812084
Source
Medline
License
Unknown

Abstract

An efficient and redox-neutral naphthol synthesis has been realized via rhodium(iii) catalyzed C-H activation of α-carbonyl nitrones and annulation with alkynes, where the nitrone group functioned as a traceless directing group.

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