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Nanorings and rods interconnected by self-assembly mimicking an artificial network of neurons.

Authors
  • Escárcega-Bobadilla, Martha V1
  • Zelada-Guillén, Gustavo A
  • Pyrlin, Sergey V
  • Wegrzyn, Marcin
  • Ramos, Marta M D
  • Giménez, Enrique
  • Stewart, Andrew
  • Maier, Gerhard
  • Kleij, Arjan W
  • 1 1] Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona, Spain [2]. , (Spain)
Type
Published Article
Journal
Nature Communications
Publisher
Springer Nature
Publication Date
Jan 01, 2013
Volume
4
Pages
2648–2648
Identifiers
DOI: 10.1038/ncomms3648
PMID: 24177669
Source
Medline
License
Unknown

Abstract

Molecular electronics based on structures ordered as neural networks emerges as the next evolutionary milestone in the construction of nanodevices with unprecedented applications. However, the straightforward formation of geometrically defined and interconnected nanostructures is crucial for the production of electronic circuitry nanoequivalents. Here we report on the molecularly fine-tuned self-assembly of tetrakis-Schiff base compounds into nanosized rings interconnected by unusually large nanorods providing a set of connections that mimic a biological network of neurons. The networks are produced through self-assembly resulting from the molecular conformation and noncovalent intermolecular interactions. These features can be easily generated on flat surfaces and in a polymeric matrix by casting from solution under ambient conditions. The structures can be used to guide the position of electron-transporting agents such as carbon nanotubes on a surface or in a polymer matrix to create electrically conducting networks that can find direct use in constructing nanoelectronic circuits.

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