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N-metalated imines by reaction of 1,1-diethoxybut-2-ene with aromatic nitriles, as useful intermediates for the synthesis of substituted pyrimidines and cyclopentenones.

Authors
  • Blangetti, Marco
  • Deagostino, Annamaria
  • Prandi, Cristina
  • Zavattaro, Chiara
  • Venturello, Paolo
Type
Published Article
Journal
Chemical communications (Cambridge, England)
Publication Date
Apr 14, 2008
Issue
14
Pages
1689–1691
Identifiers
DOI: 10.1039/b719462e
PMID: 18368166
Source
Medline
License
Unknown

Abstract

A new approach to the synthesis of pyrimidines and cyclopentenones is described. The method exploits the reactivity of alpha,beta-unsaturated acetals with aromatic nitriles in the presence of the Schlosser's superbase LIC-KOR.

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