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N-(2-Chloro-phen-yl)-2-methyl-benzamide.

Authors
  • Gowda, B Thimme
  • Foro, Sabine
  • Sowmya, B P
  • Fuess, Hartmut
Type
Published Article
Journal
Acta Crystallographica Section E Structure Reports Online
Publisher
International Union of Crystallography
Publication Date
Jul 05, 2008
Volume
64
Issue
Pt 8
Identifiers
DOI: 10.1107/S1600536808020229
PMID: 21203140
Source
Medline
License
Unknown

Abstract

In the structure of the title compound (N2CP2MBA), C(14)H(12)ClNO, the conformations of the N-H and C=O bonds are trans to each other. Furthermore, the conformation of the N-H bond is syn to the ortho-chloro group in the aniline ring and the C=O bond is syn to the ortho-methyl substituent in the benzoyl ring, similar to what is observed in 2-chloro-N-(2-chloro-phen-yl)benzamide and 2-methyl-N-phenyl-benzamide. The amide group makes almost the same dihedral angles of 41.2 (14) and 42.2 (13)° with the aniline and benzoyl rings, respectively, while the dihedral angle between the benzoyl and aniline rings is only 7.4 (3)°. The mol-ecules in N2CP2MBA are packed into chains through N-H⋯O hydrogen bonds.

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