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Mono- and Binuclear Gold(I) Compounds Containing Deprotonated Purines and Pyrimidines

Authors
  • Bonati, Flavio
  • Burini, Alfredo
  • Pietroni, Bianca Rosa
Type
Published Article
Journal
Zeitschrift für Naturforschung B
Publisher
Verlag der Zeitschrift für Naturforschung
Publication Date
Dec 01, 1985
Volume
40
Issue
12
Pages
1749–1752
Identifiers
DOI: 10.1515/znb-1985-1226
Source
De Gruyter
Keywords
License
Green

Abstract

In the presence of alkali and LAuCl one or two -NH - groups of a purine or pyrimidine base can be transformed into - N(AuL)- groups giving stable and soluble compounds containing one or two two-coordinated gold(I) nuclei; mononuclear LAu - Q' or binuclear LAu - Q - AuL with a monodentate Q'- or an exobidentate O-- ligand, resp. (Q'H = adenine, guanine, theobromine, theophylline, azaguanine or cytosine; QH2 - thymine or uracyl; L = triphenylphosphine)

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