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Modular synthesis of metal-organic complex arrays containing precisely designed metal sequences.

Authors
  • Sajna, Kappamveettil
  • Fracaroli, Alejandro M
  • Yaghi, Omar M
  • Tashiro, Kentaro
Type
Published Article
Journal
Inorganic Chemistry
Publisher
American Chemical Society (ACS)
Publication Date
Feb 16, 2015
Volume
54
Issue
4
Pages
1197–1199
Identifiers
DOI: 10.1021/ic5025372
PMID: 25602193
Source
Medline
License
Unknown

Abstract

A modular synthetic approach is reported for the synthesis of heterometallic metal-organic complex arrays (MOCAs). Modules of four metal centers containing three different metals copper(II), nickel(II), platinum(II), or ruthenium(II) are prepared using a solid-phase polypeptide synthesis technique and then linked in solution to make MOCAs of eight metal centers as linear, T-branched, and H-branched compounds. The MOCA molecular topologies thus have specific unique linear and branched sequences of metals along the peptide backbone.

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