Affordable Access

deepdyve-link deepdyve-link
Publisher Website

Modular synthesis of metal-organic complex arrays containing precisely designed metal sequences.

Authors
Type
Published Article
Journal
Inorganic Chemistry
1520-510X
Publisher
American Chemical Society
Publication Date
Volume
54
Issue
4
Pages
1197–1199
Identifiers
DOI: 10.1021/ic5025372
PMID: 25602193
Source
Medline
License
Unknown

Abstract

A modular synthetic approach is reported for the synthesis of heterometallic metal-organic complex arrays (MOCAs). Modules of four metal centers containing three different metals copper(II), nickel(II), platinum(II), or ruthenium(II) are prepared using a solid-phase polypeptide synthesis technique and then linked in solution to make MOCAs of eight metal centers as linear, T-branched, and H-branched compounds. The MOCA molecular topologies thus have specific unique linear and branched sequences of metals along the peptide backbone.

Statistics

Seen <100 times