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{Mo24Fe12} macrocycles: anion templation with large polyoxometalate guests.

Authors
  • Fang, Xikui
  • Hansen, Laura
  • Haso, Fadi
  • Yin, Panchao
  • Pandey, Abhishek
  • Engelhardt, Larry
  • Slowing, Igor
  • Li, Tao
  • Liu, Tianbo
  • Luban, Marshall
  • Johnston, David C
Type
Published Article
Journal
Angewandte Chemie International Edition in English
Publisher
Wiley (John Wiley & Sons)
Publication Date
Sep 27, 2013
Volume
52
Issue
40
Pages
10500–10504
Identifiers
DOI: 10.1002/anie.201304887
PMID: 23943611
Source
Medline
Keywords
License
Unknown

Abstract

POM and circumstance: Nanometer-sized polyoxometalates (POMs) bring a new direction to anion-templated supramolecular chemistry. The Keggin (left) and Dawson-type (right) polyoxoanions direct the assembly of giant metallomacrocycles through an array of weak hydrogen-bonding interactions. The concerted action of multiple hydrogen bonds keeps the templating guests embedded within the hosts, even in the solution state.

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