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{Mo24Fe12} macrocycles: anion templation with large polyoxometalate guests.

Authors
Type
Published Article
Journal
Angewandte Chemie International Edition in English
1521-3773
Publisher
Wiley Blackwell (John Wiley & Sons)
Publication Date
Volume
52
Issue
40
Pages
10500–10504
Identifiers
DOI: 10.1002/anie.201304887
PMID: 23943611
Source
Medline
Keywords
  • Anion Templation
  • Hydrogen Bonds
  • Magnetism
  • Polyoxometalates
  • Supramolecular Chemistry

Abstract

POM and circumstance: Nanometer-sized polyoxometalates (POMs) bring a new direction to anion-templated supramolecular chemistry. The Keggin (left) and Dawson-type (right) polyoxoanions direct the assembly of giant metallomacrocycles through an array of weak hydrogen-bonding interactions. The concerted action of multiple hydrogen bonds keeps the templating guests embedded within the hosts, even in the solution state.

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