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MgFePO4F as a feasible cathode material for magnesium batteries

Authors
  • Huang, Zhen-Dong1
  • Masese, Titus1
  • Orikasa, Yuki1
  • Mori, Takuya1
  • Taketoshi Minato2
  • Tassel, Cedric3
  • Kobayashi, Yoji3
  • Kageyama, Hiroshi3
  • Uchimoto, Yoshiharu1
Type
Published Article
Journal
Journal of Materials Chemistry A
Publisher
Royal Society of Chemistry (RSC)
Publication Date
Jan 25, 2014
Volume
2
Identifiers
DOI: 10.1039/c4ta01779j
Source
MyScienceWork
License
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Abstract

A stoichiometric MgFePO4F (MFPF) is synthesised by using a solid-state carbothermal method. Its monoclinic framework, possessing an entire cationic mixing of Mg2+ and Fe2+, is validated via both crystal structure analysis and simulation. Interestingly, MFPF exhibits a relatively high potential (∼2.6 V vs. Mg/Mg2+) and good cyclic stability with an encouraging capacity (∼53 mA h g−1), bringing MFPF to the fore as a promising cathode material for magnesium batteries.

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