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Metal exchange reactions between cadmium protoporphyrin and cobalt and zinc chlorides in acetonitrile and dimethyl sulfoxide

Authors
  • Zvezdina, S. V.1
  • Berezin, M. B.1
  • Berezin, B. D.1
  • 1 Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya ul. 1, Ivanovo, 153045, Russia , Ivanovo (Russia)
Type
Published Article
Journal
Russian Journal of Inorganic Chemistry
Publisher
Nauka/Interperiodica
Publication Date
Jan 01, 2006
Volume
51
Issue
1
Pages
112–117
Identifiers
DOI: 10.1134/S0036023606010189
Source
Springer Nature
Keywords
License
Yellow

Abstract

Metal exchange between cadmium protoporphyrin CdPP and zinc and cobalt chlorides in dimethyl sulfoxide (DMSO) and acetonitrile (AN) was studied by spectrophotometry. Comparative analysis of the data on metal exchange between CdPP and ZnCl2 in DMSO and between CdPP and CoCl2 in AN was performed. The possible exchange mechanisms were considered. The results were compared with the data on cadmium mesoporphyrin exchange with zinc and cobalt.

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