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Mechanochemical ruthenium-catalyzed olefin metathesis.

Authors
  • Do, Jean-Louis
  • Mottillo, Cristina
  • Tan, Davin
  • Štrukil, Vjekoslav
  • Friščić, Tomislav
Type
Published Article
Journal
Journal of the American Chemical Society
Publisher
American Chemical Society
Publication Date
Feb 25, 2015
Volume
137
Issue
7
Pages
2476–2479
Identifiers
DOI: 10.1021/jacs.5b00151
PMID: 25668586
Source
Medline
License
Unknown

Abstract

We describe the development of a mechanochemical approach for Ru-catalyzed olefin metathesis, including cross-metathesis and ring-closing metathesis. The method uses commercially available catalysts to achieve high-yielding, rapid, room-temperature metathesis of solid or liquid olefins on a multigram scale using either no or only a catalytic amount of a liquid.

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