Affordable Access

Long-lived platinum(II) diimine complexes with broadband excited-state absorption: efficient nonlinear absorbing materials.

Authors
  • Liu, Rui
  • Azenkeng, Alexander
  • Li, Yuhao
  • Sun, Wenfang
Type
Published Article
Journal
Dalton Transactions
Publisher
The Royal Society of Chemistry
Publication Date
Oct 28, 2012
Volume
41
Issue
40
Pages
12353–12357
Identifiers
PMID: 22972235
Source
Medline
License
Unknown

Abstract

Platinum(II) diimine complexes with naphthalimide substituted fluorenylacetylide ligands are synthesized and characterized. The complexes exhibit long-lived (3)ILCT or (3)ILCT/(3)MLCT/(3)LLCT excited states (τ = ~20-30 μs) and broadband triplet transient absorption in the visible-NIR region. Nonlinear transmission experiments at 532 nm demonstrate that these complexes are efficient nonlinear absorbing materials.

Report this publication

Statistics

Seen <100 times