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A layered erbium phosphonate in pseudo-D(5h) symmetry exhibiting field-tunable magnetic relaxation and optical correlation.

Authors
  • Ren, Min
  • Bao, Song-Song
  • Ferreira, Rute A S
  • Zheng, Li-Min
  • Carlos, Luis D
Type
Published Article
Journal
Chemical Communications
Publisher
The Royal Society of Chemistry
Publication Date
Jul 21, 2014
Volume
50
Issue
57
Pages
7621–7624
Identifiers
DOI: 10.1039/c4cc02085e
PMID: 24889410
Source
Medline
License
Unknown

Abstract

A layered erbium(III) phosphonate compound, [Er(notpH4)(H2O)]ClO4·3H2O (1), in which the Er(III) ion has a pseudo-D5h symmetry exhibits field tunable multiple magnetic relaxation. The near-IR emission spectrum of 1, excited at 1064 nm (Nd:YAG laser), provides a direct probe of the crystal field splitting correlated to the magnetic data.

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