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Iron-catalyzed oxidative coupling of arylboronic acids with benzene derivatives through homolytic aromatic substitution.

Authors
  • Uchiyama, Nanase
  • Shirakawa, Eiji
  • Nishikawa, Ryo
  • Hayashi, Tamio
Type
Published Article
Journal
Chemical Communications
Publisher
The Royal Society of Chemistry
Publication Date
Nov 14, 2011
Volume
47
Issue
42
Pages
11671–11673
Identifiers
DOI: 10.1039/c1cc14694g
PMID: 21952466
Source
Medline
License
Unknown

Abstract

Fe(OTf)(3)-1,10-phenanthroline catalyzes oxidative coupling of arylboronic acids with benzene derivatives using t-BuOOt-Bu as an oxidant. The reaction proceeds through homolytic aromatic substitution with aryl radicals generated from arylboronic acids and t-BuO˙.

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