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Intriguing mechanistic labyrinths in gold(I) catalysis.

Authors
  • Obradors, Carla1
  • Echavarren, Antonio M
  • 1 Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona, Spain. [email protected] , (Spain)
Type
Published Article
Journal
Chemical Communications
Publisher
The Royal Society of Chemistry
Publication Date
Jan 04, 2014
Volume
50
Issue
1
Pages
16–28
Identifiers
DOI: 10.1039/c3cc45518a
PMID: 24176910
Source
Medline
License
Unknown

Abstract

Many mechanistically intriguing reactions have been developed in the last decade using gold(I) as catalyst. Here we review the main mechanistic proposals in gold-catalysed activation of alkynes and allenes, in which this metal plays a central role by stabilising a variety of complex cationic intermediates.

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