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Hydrothermal syntheses and structural characterizations of organic-inorganic hybrid materials of the M(II)-ligand/vanadium oxide system (M(II) = Mn(II), Cu(II) and Zn(II); ligand = 2,2'-bipyridine and 1,10-phenanthroline).

Authors
  • Yi, Zhi-Hui
  • Cui, Xiao-Bing
  • Zhang, Xiao
  • Yu, Jie-Hui
  • Lu, Jing
  • Xu, Ji-Qing
  • Yang, Guang-Di
  • Wang, Tie-Gang
  • Yu, Hai-Hui
  • Duan, Wei-Jie
Type
Published Article
Journal
Dalton transactions (Cambridge, England : 2003)
Publication Date
Jun 07, 2007
Issue
21
Pages
2115–2120
Identifiers
PMID: 17514331
Source
Medline
License
Unknown

Abstract

Three organic-inorganic hybrid compounds [Mn(bpy)V(bpy)V(3)O(11)] (bpy = 2,2'-bipyridine) (1), [Cu(bpy)V(2)O(6)] (2) and [Zn(phen)3][V(2)O(6)].10H(2)O (phen = 1,10-phenanthroline) (3) have been synthesized hydrothermally. Single crystal X-ray diffraction analyses revealed that compound 1 is the first example of bpy units coordinating to different transition metals in one molecule. Compound 2 is a new isomer of [Cu(bpy)V(2)O(6)] which was named the gamma-isomer by us. In compound 3, a 2-D water sheet with big holes filled by the "naked" [V(4)O(12)](4-) clusters is found.

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