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Highly stereoselective, thermodynamically controlled and reversible formation of a new P-chiral phosphine.

Authors
  • Komarov, Igor V
  • Spannenberg, Anke
  • Holz, Jens
  • Börner, Armin
Type
Published Article
Journal
Chemical communications (Cambridge, England)
Publication Date
Sep 07, 2003
Issue
17
Pages
2240–2241
Identifiers
PMID: 13678220
Source
Medline
License
Unknown

Abstract

The highly stereoselective formation of a chiral alpha-hydroxyphospholane under very mild condition is reported, taking place on a camphor skeleton by an intramolecular thermodynamically controlled and reversible addition of an epimeric secondary phosphine group to a carbonyl group.

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