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Heteroleptic tris-cyclometalated iridium(III) complexes supported by an o-carboranyl-pyridine ligand.

Authors
  • Bae, Hye Jin1
  • Kim, Hyungjun
  • Lee, Kang Mun
  • Kim, Taewon
  • Eo, Maengsun
  • Lee, Yoon Sup
  • Do, Youngkyu
  • Lee, Min Hyung
  • 1 Department of Chemistry, KAIST, Daejeon, 305-701, Republic of Korea. , (North Korea)
Type
Published Article
Journal
Dalton Transactions
Publisher
The Royal Society of Chemistry
Publication Date
Jun 28, 2013
Volume
42
Issue
24
Pages
8549–8552
Identifiers
DOI: 10.1039/c3dt51019k
PMID: 23661164
Source
Medline
License
Unknown

Abstract

Heteroleptic tris-cyclometalated Ir(III) complexes supported by the o-carboranyl-pyridine (CBpy) as a novel C^N chelating ligand were synthesized and characterized. While the CBpy ligand contributes to the electronic stabilization of complexes, their photophysical properties are dominated by 2-arylpyridine ligands.

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