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Giant pores in a chromium 2,6-naphthalenedicarboxylate open-framework structure with MIL-101 topology.

Authors
Type
Published Article
Journal
Angewandte Chemie International Edition in English
1521-3773
Publisher
Wiley Blackwell (John Wiley & Sons)
Publication Date
Volume
48
Issue
21
Pages
3791–3794
Identifiers
DOI: 10.1002/anie.200805980
PMID: 19191364
Source
Medline
License
Unknown

Abstract

Large, larger, ... Replacement of 1,4-benzenedicarboxylate by 2,6-naphthalenedicarboxylate in the MIL-101 structure leads to an isoreticular mesoporous framework containing cages with diameters of 39 and 46 A. High-throughput methods are employed to determine appropriate reaction conditions. The microcrystalline compound is characterized by molecular simulation techniques, powder X-ray diffraction, N(2)-sorption, and TEM investigations.

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