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Free-Energy Density Functional of Ions at a Dielectric Interface.

Authors
  • Gillespie, Dirk
Type
Published Article
Journal
The Journal of Physical Chemistry Letters
Publisher
American Chemical Society
Publication Date
May 19, 2011
Volume
2
Issue
10
Pages
1178–1182
Identifiers
DOI: 10.1021/jz2001908
PMID: 26295322
Source
Medline
Keywords
License
Unknown

Abstract

Ions at dielectric interfaces are found in a wide range of applications including biology, nanofluidics, and fuel cells. Often, the excluded volume of the ions has first-order effects on measured properties. Here, density functional theory of fluids is used to develop a statistical mechanical theory of how ions (charged hard spheres of different sizes) arrange around a dielectric interface.

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