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Formation of redox-active self-assembled polyelectrolyte-surfactant complexes integrating glucose oxidase on electrodes: Influence of the self-assembly solvent on the signal generation.

Authors
  • Cortez, M Lorena1
  • Ceolín, Marcelo2
  • Azzaroni, Omar3
  • Battaglini, Fernando4
  • 1 INQUIMAE, Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 2, C1428EHA Buenos Aires, Argentina; Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas (INIFTA), Departamento de Química, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, CONICET, CC 16 Suc. 4, 1900 La Plata, Argentina. , (Argentina)
  • 2 Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas (INIFTA), Departamento de Química, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, CONICET, CC 16 Suc. 4, 1900 La Plata, Argentina. , (Argentina)
  • 3 Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas (INIFTA), Departamento de Química, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, CONICET, CC 16 Suc. 4, 1900 La Plata, Argentina. Electronic address: [email protected] , (Argentina)
  • 4 INQUIMAE, Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 2, C1428EHA Buenos Aires, Argentina. Electronic address: [email protected] , (Argentina)
Type
Published Article
Journal
Bioelectrochemistry (Amsterdam, Netherlands)
Publication Date
Oct 01, 2015
Volume
105
Pages
117–122
Identifiers
DOI: 10.1016/j.bioelechem.2015.06.001
PMID: 26094060
Source
Medline
License
Unknown

Abstract

In this work the effects of the self-assembly solvent on the structure and electrochemical behavior of redox-active polyelectrolyte–surfactant complexes cast on electrode supports from aqueous and DMF solutions are presented. The complex studied is formed by complexation of osmium complex-modified polyallylamine (OsPA) with dodecyl sulfate (DS) surfactants. The structure of the films was characterized by GISAXS, showing that films present a lamellar mesostructure. However, when they are exposed to humid environments, films cast from aqueous solutions (OsPA–DSaq) undergo a structural transition that ultimately leads to the disappearance of the mesostructural order. On the other hand, OsPA–DS films cast from DMF solutions (OsPA–DSorg) revealed no significant changes upon exposure to humid environments. Both types of films were exposed to glucose oxidase (GOx), showing similar adsorption characteristics. Notwithstanding these similarities in GOx and content, OsPA–DSaq films revealed a more sensitive bioelectrocatalytical response to glucose as compared to OsPA–DSorg films.

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