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Formation of derivatives of benzofuran, indole, and cinnoline in the reaction of 7-(N-morpholinyl)-7-methyl-8a-hydroxy-4,5,8,8a-tetrahydro-7H-pyrrolo[3,2-e]-2,1,3-benzoxadiazole 6-oxide with nucleophilic reagents

Authors
  • Samsonov, V. A.
  • Volodarskii, L. B.
Type
Published Article
Journal
Chemistry of Heterocyclic Compounds
Publisher
Kluwer Academic Publishers-Plenum Publishers
Publication Date
Mar 01, 1998
Volume
34
Issue
3
Pages
271–274
Identifiers
DOI: 10.1007/BF02290715
Source
Springer Nature
Keywords
License
Yellow

Abstract

7-(N-Morpholinyl)-7-methyl-8a-hydroxy-4,5,8,8a-tetrahydro-7H-pyrrolo[3,2-e]-2,1,3-benzoxadiazole 6-oxide behaves as the synthetic equivalent of a 1,4-dicarbonyl compound in reactions with amines, dioxime, and hydrazine to give derivatives of benzofuran, indole, 1,4-dioxime, and pyridazine. This compound also undergoes reactions characteristic for nitrones, adding water and a hydride ion.

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