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Formal synthesis of (+)-nakadomarin A.

Authors
  • Inagaki, Fuyuhiko
  • Kinebuchi, Masahiko
  • Miyakoshi, Naoki
  • Mukai, Chisato
Type
Published Article
Journal
Organic Letters
Publisher
American Chemical Society
Publication Date
Apr 16, 2010
Volume
12
Issue
8
Pages
1800–1803
Identifiers
DOI: 10.1021/ol100412f
PMID: 20232853
Source
Medline
License
Unknown

Abstract

The formal synthesis of (+)-nakadomarin A was completed. The significant points of this synthesis are the highly stereoselective formation of the diazatricyclo[6.4.0.0(1,5)]dodecane skeleton (A, B, and D rings) based on the Pauson-Khand reaction and novel furan ring (C ring) formation, using the vinyl residue of the Pauson-Khand product.

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