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Flexibility of ZIF-8 materials studied using 129Xe NMR.

Authors
  • Springuel-Huet, Marie-Anne
  • Nossov, Andrei
  • Guenneau, Flavien
  • Gédéon, Antoine
Type
Published Article
Journal
Chemical Communications
Publisher
The Royal Society of Chemistry
Publication Date
Aug 28, 2013
Volume
49
Issue
67
Pages
7403–7405
Identifiers
DOI: 10.1039/c3cc43119c
PMID: 23862180
Source
Medline
License
Unknown

Abstract

Structural changes in a porous hybrid inorganic-organic ZIF-8 compound have been explored using hyperpolarized (129)Xe NMR of adsorbed xenon at various temperatures. Upon xenon adsorption at low temperature, the organic linkers undergo a reorientation leading to a stepwise increase in xenon adsorption and in chemical shift.

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