The first total synthesis of (+)-mucosin has been completed allowing assignment of the absolute stereochemistry of the natural product. A zirconium induced co-cyclisation was utilised to install the correct stereochemistry of the four contiguous stereocentres around the unusual bicyclo[4.3.0]nonene core.
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The corresponding record at NLM can be accessed at https://www.ncbi.nlm.nih.gov/pubmed/22358150