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Fingerprinting the tertiary structure of electroadsorbed lysozyme at soft interfaces by electrostatic spray ionization mass spectrometry

Authors
  • Alvarez De Eulate, Eva
  • Qiao, L.
  • Scanlon, M.
  • Girault, H.
  • Arrigan, Damien
Publication Date
Jan 01, 2014
Source
[email protected]
License
Unknown

Abstract

Lysozyme can be electrochemically detected after adsorption at an electrified gel–water interface. Ex situ characterization by electrostatic spray ionization mass spectrometry provides insights into the interfacial detection mechanism by allowing changes to the tertiary structure of electroadsorbed lysozyme to be fingerprinted for the first time.

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