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An efficient preparation of optically active (E)-γ-hydroxy-α,β-unsaturated phenyl sulfones using lipase-mediated acylations

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
32
Issue
38
Identifiers
DOI: 10.1016/s0040-4039(00)93455-5

Abstract

Abstract (E)-γ-Hydroxy-α,β-unsaturated phenyl sulfones have been efficiently resolved via irreversible enzymatic acylation with lipase PS ( pseudomonas cepacia) and vinyl acetate. This process has been applied to the synthesis of the aggregation pheromone (−)-(3S,4S)-4-methyl-3-heptanol.

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