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Ferrocene-based Lewis acids and Lewis pairs: Synthesis and structural characterization

Authors
  • SUDHAKAR, PAGIDI1
  • THILAGAR, PAKKIRISAMY1
  • 1 Indian Institute of Science, Department of Inorganic and Physical Chemistry, Bangalore, 560 012, India , Bangalore (India)
Type
Published Article
Journal
Journal of Chemical Sciences
Publisher
Springer-Verlag
Publication Date
Jan 01, 2013
Volume
125
Issue
1
Pages
41–49
Identifiers
DOI: 10.1007/s12039-012-0356-8
Source
Springer Nature
Keywords
License
Yellow

Abstract

Optically active Lewis acids and Lewis pairs were synthesized and characterized by multinuclear NMR, UV/Vis spectroscopy and elemental analysis. Optical rotation measurements were carried out and the absolute configuration of the new chiral molecules confirmed by single crystal X-ray diffraction. Graphical AbstractOptically active SP and RP isomers of 1-phosphino-2-borylferrocenes were synthesized by adopting a simple synthetic approach and using a single precursor.

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