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A highly efficient synthetic route to ketones through sequential coupling reactions of grignard reagents withs-phenyl carbonochloridothioate in the presence of nickel or iron catalysts

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
26
Issue
30
Identifiers
DOI: 10.1016/s0040-4039(00)89199-6

Abstract

Abstract The sequential coupling reactions of Grignard reagents with S phenyl carbonochloridothioate in the presence of nickel(II) or iron(III) catalysts provides a very mild and straightforward route to symmetrical and unsymmetrical aliphatic and aromatic ketones.

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