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A Raman and i.r. spectroscopic investigation of the intermolecular interactions in solid and liquid POCl3and PSCl3

Authors
Journal
Spectrochimica Acta Part A Molecular Spectroscopy
0584-8539
Publisher
Elsevier
Publication Date
Volume
32
Issue
3
Identifiers
DOI: 10.1016/0584-8539(76)80105-5

Abstract

Abstract Type and strength of intermolecular interactions in solid and liquid POCl 3 and PSCl 3 were investigated from the Raman and i.r. spectra and related to the X-ray structural results for solid POCl 3. Most information about the type of these interactions was obtained from anomalies in the isotope splitting of the symmetric PCl stretching modes.

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