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Iron(III) dimethoxide compounds

Authors
Journal
Journal of Inorganic and Nuclear Chemistry
0022-1902
Publisher
Elsevier
Publication Date
Volume
25
Issue
7
Identifiers
DOI: 10.1016/0022-1902(63)80368-1

Abstract

Abstract The preparation of various anhydrous iron(III) compounds and their conversion to iron(III) dimethoxides of the type Fe(OCH 3) 2X are described. The formate and the acetate were synthesized by improved, convenient methods and new alkanoates (stearate, pivalate, benzoate, adipate, chloroacetate and trichloroacetate) were obtained. Also, the nitrate and compounds with the anions of ethyl acetoacetate, dibenzoylmethane and thenoyltrifluoroacetone were made. Attempts to prepare derivatives of strong acids and complexing agents are briefly discussed.

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