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Silicon in organic synthesis. 16. A short synthesis of (+±)-α-vetispirene

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
23
Issue
32
Identifiers
DOI: 10.1016/s0040-4039(00)87576-0

Abstract

Abstract α-Vetispirene, a prototypical [4.5]spirobicyclic sesquiterpene, has been prepared in an efficient five-step reaction sequence beginning with α-trimethylsilyl cyclopropanecarboxaldehyde. A new desiliconative alkylation is featured.

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