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Facile NBS/DMSO mediated dibromination of olefins including selected natural products and glycals

Authors
  • Ul Lah, Hafiz1
  • Mir, Shabir Ahmad1, 2
  • Hussain, Gulzar1
  • Wani, Rafiq Ahmad1
  • Yousuf, Syed Khalid1, 2
  • 1 CSIR-Indian Institute of Integrative Medicine (CSIR-IIIM), Sanatnagar, Srinagar, J & K, 190005, India , Sanatnagar, Srinagar (India)
  • 2 Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, Uttar Pradesh-, 201 002, India , Ghaziabad (India)
Type
Published Article
Journal
Journal of Chemical Sciences
Publisher
Springer India
Publication Date
Feb 02, 2022
Volume
134
Issue
1
Identifiers
DOI: 10.1007/s12039-021-02003-3
Source
Springer Nature
Keywords
Disciplines
  • Regular Article
License
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Abstract

A highly chemo- and diastereoselective vic-dibromination of olefins has been developed. The process employs a readily available N-Bromosuccinimide (NBS)/DMSO reagent system as a bromine source. High substrate scope, simple reaction conditions, application to natural products and glycals makes the process very attractive.Graphical abstractA highly chemo- and diastereoselective vic-dibromination of olefins has been developed. The process employs a readily available N-Bromosuccinimide (NBS)/DMSO reagent system as a bromine source. High substrate scope, simple reaction conditions, application to natural products and glycals makes the process very attractive.

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