Novel bioactive films based on pectin and cellulose (PC) with different loadings of tea polyphenols and cinnamaldehyde were successfully prepared. A thermal stability was tested, and the results showed that the thermal stability decreased slightly after loading with cinnamaldehyde and tea polyphenols, compared to PC films. The antimicrobial and antioxidant capacities were also investigated. Results showed that PC composite films had good DPPH radical and hydroxyl radical scavenging activities and excellent antibacterial activities against Escherichia coli, Candida albicans and Staphylococcus aureus. Based on the results, the great antioxidant and antibacterial activities of the tea polyphenol and cinnamaldehyde loaded PC films make them suitable for food packaging and preservation.