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Preparation and selective cleavage reactions of boron-zirconium 1,1-bimetalloalkanes

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
34
Issue
26
Identifiers
DOI: 10.1016/s0040-4039(00)60510-5

Abstract

Abstract Hydrozirconation of various vinyl-9-BBN derivatives with Schwartz's reagent, H(Cl)ZrCp 2, provides 1,1-dimetalloalkanes of boron and zirconium. By selective cleavage of carbon-zirconium bond in these 1,1-dimetallics with bromine, a convenient method for preparation of α-bromoboranes was achieved.

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